Dr. Danila Barskiy

Profile

Academic positionLecturer, Assistant Professor, Researcher
Research fieldsAnalytical Chemistry,Medical Physics, Biomedical Engineering
KeywordsZero- and Ultralow Magnetic Fields, Microfluidics, Hyperpolarization, Nuclear Magnetic Resonance, Parahydrogen

Current contact address

CountryGermany
CityMainz
InstitutionJohannes Gutenberg-Universität Mainz
InstituteInstitut für Physik - Quanten-, Atom- und Neutronenphysik (QUANTUM)

Host during sponsorship

Prof. Dr. Dmitry BudkerInstitut für Physik - Quanten-, Atom- und Neutronenphysik (QUANTUM), Johannes Gutenberg-Universität Mainz, Mainz
Start of initial sponsorship01/10/2020

Program(s)

2020Sofja Kovalevskaja Award Programme

Publications (partial selection)

2021Sheberstov, Kirill F and Chuchkova, Liubov and Hu, Yinan and Zhukov, Ivan V and Kiryutin, Alexey S and Eshtukov, Artur V and Cheshkov, Dmitry A and Barskiy, Danila A and Blanchard, John W and Budker, Dmitry and others: Photochemically induced dynamic nuclear polarization of heteronuclear singlet order. In: The Journal of Physical Chemistry Letters, 12, 2021, 4686--4691
2021Knecht, Stephan and Blanchard, John W and Barskiy, Danila and Cavallari, Eleonora and Dagys, Laurynas and Van Dyke, Erik and Tsukanov, Maksim and Bliemel, Bea and Münnemann, Kerstin and Aime, Silvio and others: Rapid hyperpolarization and purification of the metabolite fumarate in aqueous solution. In: Proceedings of the National Academy of Sciences, 118, 2021,
2021Blanchard, John W and Ripka, Barbara and Suslick, Benjamin A and Gelevski, Dario and Wu, Teng and Münnemann, Kerstin and Barskiy, Danila A and Budker, Dmitry: Towards large-scale steady-state enhanced nuclear magnetization with in situ detection. In: Magnetic Resonance in Chemistry, 2021,
2021Put, Piotr and Pustelny, Szymon and Budker, Dmitry and Druga, Emanuel and Sjolander, Tobias F and Pines, Alexander and Barskiy, Danila A: Zero-to ultralow-field NMR spectroscopy of small biomolecules. In: Analytical Chemistry, 93, 2021, 3226--3232
2020Knecht, Stephan and Barskiy, Danila A and Buntkowsky, Gerd and Ivanov, Konstantin L: Theoretical description of hyperpolarization formation in the SABRE-relay method. In: The Journal of Chemical Physics, 153, 2020, 164106
2020Barskiy, Danila and Blanchard, John and Reh, Moritz and Sjoelander, Tobias and Pines, Alexander and Budker, Dmitry: Zero-Field J-spectroscopy of Quadrupolar Nuclei. In: arXiv preprint arXiv:2011.05618, 2020,
2019Knecht, Stephan and Hadjiali, Sara and Barskiy, Danila A and Pines, Alexander and Sauer, Grit and Kiryutin, Alexey S and Ivanov, Konstantin L and Yurkovskaya, Alexandra V and Buntkowsky, Gerd: Indirect Detection of Short-Lived Hydride Intermediates of Iridium N-Heterocyclic Carbene Complexes via Chemical Exchange Saturation Transfer Spectroscopy. In: The Journal of Physical Chemistry C, 123, 2019, 16288--16293
2019Barskiy, Danila A and Knecht, Stephan and Yurkovskaya, Alexandra V and Ivanov, Konstantin L: SABRE: Chemical kinetics and spin dynamics of the formation of hyperpolarization. In: Progress in nuclear magnetic resonance spectroscopy, 114, 2019, 33--70
2019Barskiy, Danila A and Tayler, Michael CD and Marco-Rius, Irene and Kurhanewicz, John and Vigneron, Daniel B and Cikrikci, Sevil and Aydogdu, Ayca and Reh, Moritz and Pravdivtsev, Andrey N and Hövener, Jan-Bernd and others: Zero-field nuclear magnetic resonance of chemically exchanging systems. In: Nature communications, 10, 2019, 1--9
2018Kovtunov, Kirill V and Pokochueva, Ekaterina V and Salnikov, Oleg G and Cousin, Samuel F and Kurzbach, Dennis and Vuichoud, Basile and Jannin, Sami and Chekmenev, Eduard Y and Goodson, Boyd M and Barskiy, Danila A and others: Hyperpolarized NMR Spectroscopy: d-DNP, PHIP, and SABRE Techniques. In: Chemistry--An Asian Journal, 13, 2018, 1857--1871
2018Barskiy, Danila A and Ke, Lucia A and Li, Xingyang and Stevenson, Vincent and Widarman, Nevin and Zhang, Hao and Truxal, Ashley and Pines, Alexander: Rapid catalyst capture enables metal-free para-hydrogen-based hyperpolarized contrast agents. In: The journal of physical chemistry letters, 9, 2018, 2721--2724
2018Burueva, Dudari B and Kovtunov, Kirill V and Bukhtiyarov, Andrey V and Barskiy, Danila A and Prosvirin, Igor P and Mashkovsky, Igor S and Baeva, Galina N and Bukhtiyarov, Valerii I and Stakheev, Aleksandr Yu and Koptyug, Igor V: Selective Single-Site Pd- In Hydrogenation Catalyst for Production of Enhanced Magnetic Resonance Signals using Parahydrogen. In: Chemistry--A European Journal, 24, 2018, 2547--2553
2017Barskiy, Danila A and Kovtunov, Kirill V and Gerasimov, Evgeny Y and Phipps, M Anthony and Salnikov, Oleg G and Coffey, Aaron M and Kovtunova, Larisa M and Prosvirin, Igor P and Bukhtiyarov, Valerii I and Koptyug, Igor V and others: 2D mapping of NMR signal enhancement and relaxation for heterogeneously hyperpolarized propane gas. In: The Journal of Physical Chemistry C, 121, 2017, 10038--10046
2017Bales, Liana B and Kovtunov, Kirill V and Barskiy, Danila A and Shchepin, Roman V and Coffey, Aaron M and Kovtunova, Larisa M and Bukhtiyarov, Andrey V and Feldman, Matthew A and Bukhtiyarov, Valerii I and Chekmenev, Eduard Y and others: Aqueous, heterogeneous para-hydrogen-induced 15N polarization. In: The Journal of Physical Chemistry C, 121, 2017, 15304--15309
2017Burueva, Dudari B and Romanov, Alexey S and Salnikov, Oleg G and Zhivonitko, Vladimir V and Chen, Yu-Wen and Barskiy, Danila A and Chekmenev, Eduard Y and Hwang, Dennis W and Kovtunov, Kirill V and Koptyug, Igor V: Extending the lifetime of hyperpolarized propane gas through reversible dissolution. In: The Journal of Physical Chemistry C, 121, 2017, 4481--4487
2017Colell, Johannes FP and Logan, Angus WJ and Zhou, Zijian and Shchepin, Roman V and Barskiy, Danila A and Ortiz Jr, Gerardo X and Wang, Qiu and Malcolmson, Steven J and Chekmenev, Eduard Y and Warren, Warren S and others: Generalizing, extending, and maximizing nitrogen-15 hyperpolarization induced by parahydrogen in reversible exchange. In: The Journal of Physical Chemistry C, 121, 2017, 6626--6634
2017Coffey, Aaron M and Feldman, Matthew A and Shchepin, Roman V and Barskiy, Danila A and Truong, Milton L and Pham, Wellington and Chekmenev, Eduard Y: High-resolution hyperpolarized in vivo metabolic 13C spectroscopy at low magnetic field (48.7 mT) following murine tail-vein injection. In: Journal of Magnetic Resonance, 281, 2017, 246--252
2017Zhou, Zijian and Yu, Jin and Colell, Johannes FP and Laasner, Raul and Logan, Angus and Barskiy, Danila A and Shchepin, Roman V and Chekmenev, Eduard Y and Blum, Volker and Warren, Warren S and others: Long-lived 13C2 nuclear spin states hyperpolarized by parahydrogen in reversible exchange at microtesla fields. In: The journal of physical chemistry letters, 8, 2017, 3008--3014
2017Barskiy, Danila A and Salnikov, Oleg G and Romanov, Alexey S and Feldman, Matthew A and Coffey, Aaron M and Kovtunov, Kirill V and Koptyug, Igor V and Chekmenev, Eduard Y: NMR Spin-Lock Induced Crossing (SLIC) dispersion and long-lived spin states of gaseous propane at low magnetic field (0.05 T). In: Journal of Magnetic Resonance, 276, 2017, 78--85
2017Barskiy, Danila A and Coffey, Aaron M and Nikolaou, Panayiotis and Mikhaylov, Dmitry M and Goodson, Boyd M and Branca, Rosa T and Lu, George J and Shapiro, Mikhail G and Telkki, Ville-Veikko and Zhivonitko, Vladimir V and others: NMR hyperpolarization techniques of gases. In: Chemistry (Weinheim an der Bergstrasse, Germany), 23, 2017, 725
2017Shchepin, Roman V and Barskiy, Danila A and Coffey, Aaron M and Feldman, Matthew A and Kovtunova, Larisa M and Bukhtiyarov, Valerii I and Kovtunov, Kirill V and Goodson, Boyd M and Koptyug, Igor V and Chekmenev, Eduard Y: Robust imidazole-15N2 synthesis for high-resolution low-field (0.05 T) 15N hyperpolarized NMR spectroscopy. In: ChemistrySelect, 2, 2017, 4478--4483
2017Barskiy, Danila A and Shchepin, Roman V and Tanner, Christian PN and Colell, Johannes FP and Goodson, Boyd M and Theis, Thomas and Warren, Warren S and Chekmenev, Eduard Y: The absence of quadrupolar nuclei facilitates efficient 13C hyperpolarization via reversible exchange with parahydrogen. In: ChemPhysChem, 18, 2017, 1493--1498
2017Salnikov, Oleg G and Burueva, Dudari B and Gerasimov, Evgeniy Yu and Bukhtiyarov, Andrey V and Khudorozhkov, Alexander K and Prosvirin, Igor P and Kovtunova, Larisa M and Barskiy, Danila A and Bukhtiyarov, Valerii I and Kovtunov, Kirill V and others: The effect of oxidative and reductive treatments of titania-supported metal catalysts on the pairwise hydrogen addition to unsaturated hydrocarbons. In: Catalysis Today, 283, 2017, 82--88
2016Shchepin, Roman V and Barskiy, Danila A and Coffey, Aaron M and Theis, Thomas and Shi, Fan and Warren, Warren S and Goodson, Boyd M and Chekmenev, Eduard Y: 15N hyperpolarization of imidazole-15N2 for magnetic resonance pH sensing via SABRE-SHEATH. In: ACS sensors, 1, 2016, 640--644
2016Barskiy, Danila A and Pravdivtsev, Andrey N and Ivanov, Konstantin L and Kovtunov, Kirill V and Koptyug, Igor V: A simple analytical model for signal amplification by reversible exchange (SABRE) process. In: Physical Chemistry Chemical Physics, 18, 2016, 89--93
2016Shchepin, Roman V and Barskiy, Danila A and Coffey, Aaron M and Manzanera Esteve, Isaac V and Chekmenev, Eduard Y: Efficient Synthesis of Molecular Precursors for Para-Hydrogen-Induced Polarization of Ethyl Acetate-1-13C and Beyond. In: Angewandte Chemie, 128, 2016, 6175--6178
2016Salnikov, Oleg G and Barskiy, Danila A and Coffey, Aaron M and Kovtunov, Kirill V and Koptyug, Igor V and Chekmenev, Eduard Y: Efficient batch-mode parahydrogen-induced polarization of propane. In: Chemphyschem: a European journal of chemical physics and physical chemistry, 17, 2016, 3395
2016Shchepin, Roman V and Barskiy, Danila A and Mikhaylov, Dmitry M and Chekmenev, Eduard Y: Efficient synthesis of nicotinamide-1-15N for ultrafast NMR hyperpolarization using parahydrogen. In: Bioconjugate chemistry, 27, 2016, 878--882
2016Kovtunov, Kirill V and Romanov, Alexey S and Salnikov, Oleg G and Barskiy, Danila A and Chekmenev, Eduard Y and Koptyug, Igor V: Gas phase UTE MRI of propane and propene. In: Tomography, 2, 2016, 49
2016Barskiy, Danila A and Salnikov, Oleg G and Shchepin, Roman V and Feldman, Matthew A and Coffey, Aaron M and Kovtunov, Kirill V and Koptyug, Igor V and Chekmenev, Eduard Y: NMR SLIC sensing of hydrogenation reactions using parahydrogen in low magnetic fields. In: The Journal of Physical Chemistry C, 120, 2016, 29098--29106
2016Shchepin, Roman V and Barskiy, Danila A and Coffey, Aaron M and Goodson, Boyd M and Chekmenev, Eduard Y: NMR signal amplification by reversible exchange of sulfur-heterocyclic compounds found in petroleum. In: ChemistrySelect, 1, 2016, 2552
2016Barskiy, Danila A and Shchepin, Roman V and Coffey, Aaron M and Theis, Thomas and Warren, Warren S and Goodson, Boyd M and Chekmenev, Eduard Y: Over 20% 15N hyperpolarization in under one minute for metronidazole, an antibiotic and hypoxia probe. In: Journal of the American Chemical Society, 138, 2016, 8080--8083
2016Kovtunov, Kirill V and Barskiy, Danila A and Shchepin, Roman V and Salnikov, Oleg G and Prosvirin, Igor P and Bukhtiyarov, Andrey V and Kovtunova, Larisa M and Bukhtiyarov, Valerii I and Koptyug, Igor V and Chekmenev, Eduard Y: Production of pure aqueous 13C-hyperpolarized acetate via heterogeneous parahydrogen-induced polarization. In: Chemistry (Weinheim an der Bergstrasse, Germany), 22, 2016, 16446
2016Kovtunov, KV and Barskiy, DA and Salnikov, OG and Shchepin, RV and Coffey, AM and Kovtunova, LM and Bukhtiyarov, VI and Koptyug, IV and Chekmenev, EY: Toward production of pure 13 C hyperpolarized metabolites using heterogeneous parahydrogen-induced polarization of ethyl [1-13 C] acetate. In: RSC advances, 6, 2016, 69728--69732
2015Salnikov, Oleg G and Burueva, Dudari B and Barskiy, Danila A and Bukhtiyarova, Galina A and Kovtunov, Kirill V and Koptyug, Igor V: A Mechanistic Study of Thiophene Hydrodesulfurization by the Parahydrogen-Induced Polarization Technique. In: ChemCatChem, 7, 2015, 3508--3512
2015Corma, Avelino and Salnikov, Oleg G and Barskiy, Danila A and Kovtunov, Kirill V and Koptyug, Igor V: Back Cover: Single-Atom Gold Catalysis in the Context of Developments in Parahydrogen-Induced Polarization (Chem. Eur. J. 19/2015). In: Chemistry--A European Journal, 21, 2015, 7308--7308
2015Barskiy, Danila A and Salnikov, Oleg G and Kovtunov, Kirill V and Koptyug, Igor V: NMR signal enhancement for hyperpolarized fluids continuously generated in hydrogenation reactions with parahydrogen. In: The Journal of Physical Chemistry A, 119, 2015, 996--1006
2015Corma, Avelino and Salnikov, Oleg G and Barskiy, Danila A and Kovtunov, Kirill V and Koptyug, Igor V: Single-Atom Gold Catalysis in the Context of Developments in Parahydrogen-Induced Polarization. In: Chemistry--A European Journal, 21, 2015, 7012--7015
2015Kovtunov, Kirill V and Barskiy, Danila A and Salnikov, Oleg G and Burueva, Dudari B and Khudorozhkov, Alexander K and Bukhtiyarov, Andrey V and Prosvirin, Igor P and Gerasimov, Evgeny Y and Bukhtiyarov, Valerii I and Koptyug, Igor V: Strong Metal--Support Interactions for Palladium Supported on TiO2 Catalysts in the Heterogeneous Hydrogenation with Parahydrogen. In: ChemCatChem, 7, 2015, 2581--2584
2014Zhivonitko, Vladimir V and Kovtunov, Kirill V and Skovpin, Ivan V and Barskiy, Danila A and Salnikov, Oleg G and Koptyug, Igor V: Catalytically Enhanced NMR of Heterogeneously Catalyzed Hydrogenations. In: Understanding Organometallic Reaction Mechanisms and Catalysis, 2014, 145--186
2014Kovtunov, Kirill V and Barskiy, Danila A and Shchepin, Roman V and Coffey, Aaron M and Waddell, Kevin W and Koptyug, Igor V and Chekmenev, Eduard Y: Demonstration of heterogeneous parahydrogen induced polarization using hyperpolarized agent migration from dissolved Rh (I) complex to gas phase. In: Analytical chemistry, 86, 2014, 6192--6196
2014Salnikov, Oleg G and Barskiy, Danila A and Burueva, Dudari B and Gulyaeva, Yulia K and Balzhinimaev, Bair S and Kovtunov, Kirill V and Koptyug, Igor V: Evaluation of Activation Energies for Pairwise and Non-Pairwise Hydrogen Addition to Propyne Over Pd/Aluminosilicate Fiberglass Catalyst by Parahydrogen-Induced Polarization (PHIP). In: Applied Magnetic Resonance, 45, 2014, 1051--1061
2014Salnikov, Oleg G and Kovtunov, Kirill V and Barskiy, Danila A and Khudorozhkov, Alexander K and Inozemtseva, Elizaveta A and Prosvirin, Igor P and Bukhtiyarov, Valery I and Koptyug, Igor V: Evaluation of the mechanism of heterogeneous hydrogenation of $\alpha$, $\beta$-unsaturated carbonyl compounds via pairwise hydrogen addition. In: Acs Catalysis, 4, 2014, 2022--2028
2014Kovtunov, Kirill V and Barskiy, Danila A and Coffey, Aaron M and Truong, Milton L and Salnikov, Oleg G and Khudorozhkov, Alexander K and Inozemtseva, Elizaveta A and Prosvirin, Igor P and Bukhtiyarov, Valery I and Waddell, Kevin W and others: High-Resolution 3D Proton MRI of Hyperpolarized Gas Enabled by Parahydrogen and Rh/TiO2 Heterogeneous Catalyst. In: Chemistry--A European Journal, 20, 2014, 11636--11639
2014Coffey, Aaron M and Kovtunov, Kirill V and Barskiy, Danila A and Koptyug, Igor V and Shchepin, Roman V and Waddell, Kevin W and He, Ping and Groome, Kirsten A and Best, Quinn A and Shi, Fan and others: High-resolution low-field molecular magnetic resonance imaging of hyperpolarized liquids. In: Analytical chemistry, 86, 2014, 9042--9049
2014Barskiy, Danila A and Kovtunov, Kirill V and Koptyug, Igor V and He, Ping and Groome, Kirsten A and Best, Quinn A and Shi, Fan and Goodson, Boyd M and Shchepin, Roman V and Truong, Milton L and others: In situ and ex situ low-field NMR spectroscopy and MRI endowed by SABRE hyperpolarization. In: ChemPhysChem, 15, 2014, 4100--4107
2014Truong, Milton L and Shi, Fan and He, Ping and Yuan, Bingxin and Plunkett, Kyle N and Coffey, Aaron M and Shchepin, Roman V and Barskiy, Danila A and Kovtunov, Kirill V and Koptyug, Igor V and others: Irreversible catalyst activation enables hyperpolarization and water solubility for NMR signal amplification by reversible exchange. In: The Journal of Physical Chemistry B, 118, 2014, 13882--13889
2014Kovtunov, Kirill V and Truong, Milton L and Barskiy, Danila A and Koptyug, Igor V and Coffey, Aaron M and Waddell, Kevin W and Chekmenev, Eduard Y: Long-lived spin states for low-field hyperpolarized gas MRI. In: Chemistry--A European Journal, 20, 2014, 14629--14632
2014Kovtunov, Kirill V and Barskiy, Danila A and Salnikov, Oleg G and Khudorozhkov, Alexander K and Bukhtiyarov, Valery I and Prosvirin, Igor P and Koptyug, Igor V: Parahydrogen-induced polarization (PHIP) in heterogeneous hydrogenation over bulk metals and metal oxides. In: Chemical Communications, 50, 2014, 875--878
2014Kovtunov, Kirill V and Truong, Milton L and Barskiy, Danila A and Salnikov, Oleg G and Bukhtiyarov, Valery I and Coffey, Aaron M and Waddell, Kevin W and Koptyug, Igor V and Chekmenev, Eduard Y: Propane-d 6 heterogeneously hyperpolarized by parahydrogen. In: The Journal of Physical Chemistry C, 118, 2014, 28234--28243
2014Barskiy, Danila A and Kovtunov, Kirill V and Koptyug, Igor V and He, Ping and Groome, Kirsten A and Best, Quinn A and Shi, Fan and Goodson, Boyd M and Shchepin, Roman V and Coffey, Aaron M and others: The feasibility of formation and kinetics of NMR signal amplification by reversible exchange (SABRE) at high magnetic field (9.4 T). In: Journal of the American Chemical Society, 136, 2014, 3322--3325
2013Salnikov, Oleg G and Kovtunov, Kirill V and Barskiy, Danila A and Bukhtiyarov, Valery I and Kaptein, Robert and Koptyug, Igor V: Kinetic Study of Propylene Hydrogenation over Pt/Al 2 O 3 by Parahydrogen-Induced Polarization. In: Applied Magnetic Resonance, 44, 2013, 279--288
2013Kovtunov, Kirill V and Zhivonitko, Vladimir V and Skovpin, Ivan V and Barskiy, Danila A and Salnikov, Oleg G and Koptyug, Igor V: Toward continuous production of catalyst-free hyperpolarized fluids based on biphasic and heterogeneous hydrogenations with parahydrogen. In: The Journal of Physical Chemistry C, 117, 2013, 22887--22893
2012Kovtunov, Kirill V and Beck, Irene E and Zhivonitko, Vladimir V and Barskiy, Danila A and Bukhtiyarov, Valery I and Koptyug, Igor V: Heterogeneous addition of H 2 to double and triple bonds over supported Pd catalysts: a parahydrogen-induced polarization technique study. In: Physical Chemistry Chemical Physics, 14, 2012, 11008--11014
2012Kovtunov, Kirill V and Zhivonitko, Vladimir V and Skovpin, Ivan V and Barskiy, Danila A and Koptyug, Igor V: Parahydrogen-induced polarization in heterogeneous catalytic processes. In: Hyperpolarization Methods in NMR Spectroscopy, 2012, 123--180
2012Barskiy, Danila A and Kovtunov, Kirill V and Primo, Ana and Corma, Avelino and Kaptein, Robert and Koptyug, Igor V: Selective Hydrogenation of 1, 3-Butadiene and 1-Butyne over a Rh/Chitosan Catalyst Investigated by using Parahydrogen-Induced Polarization. In: ChemCatChem, 4, 2012, 2031--2035
n.n.Van Dyke, Erik and Tsukanov, Maksim and Bliemel, Bea and Barskiy, Danila A and Pines, Alexander: para-hydrogenation of vinylated fatty acid precursors. n.n.,