Prof. Dr. Vladimir Petrovich Fedin

Profile

Academic positionFull Professor
Research fieldsInorganic Molecular Chemistry
KeywordsCluster Complexes,, Inorganic Chemistry, Supramolecular Chemistry

Current contact address

CountryRussian Federation
CityNovosibirsk
InstitutionRussian Academy of Sciences
InstituteInstitute of Inorganic Chemistry

Host during sponsorship

Prof. Dr. Dr. h.c. Achim MüllerFakultät für Chemie, Universität Bielefeld, Bielefeld
Prof. Dr. Dr. h.c. Achim MüllerLehrstuhl für Anorganische Chemie I, Universität Bielefeld, Bielefeld
Prof. Dr. Dr. h.c. mult. Manfred ScheerInstitut für Anorganische Chemie, Universität Regensburg, Regensburg
Start of initial sponsorship01/02/1992

Program(s)

1991Humboldt Research Fellowship Programme

Publications (partial selection)

2003M. N. Sokolov, R. Hernandez-Molina, W. Clegg, Vladimir Fedin, A. Mederos: Stabilization of the previously unknown tautomer HP(OH)2 of Hypophosphorous acid as ligand; preparation of [W3(Ni(HP(OH)2))Q4(H2O)9]4+ (Q=S, Se). In: Chem. Commun., 2003, 140-141
2002Vladimir Fedin, I. V. Kalinina, A. Gerasimenko, A. Virovets: Chain-Like Cyano-Bridged Cluster-Metal Coordination Compound: Synthesis and Crystal Structure of [Cu(NH3)3][Cu(NH3)4][Cu(NH3)5][W4Te4(CN)12] 5H2O. In: Inorg. Chim. Acta, 2002, 48-51
2002M. N. Sokolov, R. Hernandez-Molina, D. N. Dybtsev, E. V. Chubarova, S. F. Solodovnikov, N. V. Pervukhina, C. Vicent, R. Llusar, Vladimir Fedin: Coordination of Phenylsulfinate PhSO2 to Mo3MS44+ Clusters (M=Ni, Pd). In: Z. Anorg. Allg. Chem., 2002, 2335-2339
2002D. G. Samsonenko, J. Lipkowski, O. A. Gerasko, A. V. Virovets, M. N. Sokolov, Vladimir Fedin, J. G. Platas, R. Hernandez-Molina, A. Mederos: Cucurbituril as a New Macrocyclic Ligand for Complexation of Lanthanide Cations in Aqueous Solutions. In: Eur. J. Inorg. Chem., 2002, 2380-2388
2002O. A. Gerasko, Vladimir Fedin: Cucurbituril: playing with molecules. In: Nature (Priroda, in Russian), 2002, 3-8
2002Vladimir Fedin, Mi-Sook Seo, D. M. Saysell, D. N. Dybtsev, M. R. J. Elsegood, W. Clegg, A. G. Sykes: Formation and properties of palladium derivatives of [Mo3Q4(H2O)9]4+: absence of similar derivatives of [W3Q4(H2O)9]4+ (Q=S, Se) . In: J. Chem. Soc., Dalton Trans., 2002, 138-143
2002Vladimir Fedin, A. G. Sykes: Molybdenum and tungsten clusters as aqua ions [M3Q4(H2O)9]4+ (M=Mo, W,; Q=S, Se) and related chalcogen-rich trinuclear clusters. In: Inorg. Synth., 2002, 162-170
2002M. N. Sokolov, D. N. Dybtsev, A. V. Virovets, Vladimir Fedin, P. Esparza, R. Hernandez-Molina, D. Fenske, A. G. Sykes: Preparation and Properties of the Aqua Ions [W4S4(H2O)12]n+ (n05, 6) and Crystal Structure of (Me2NH2)6[W4S4(NCS)12],0.5H2O. In: Inorg. Chem., 2002, 1136-1139
2002Vladimir FedinV. P. Fedin, M. N. Sokolov, D. N. Dybtsev, O. A. Gerasko, A. V. Virovets, D. Fenske: Supramolecular Assemblies of [Mo3Se4Clx(H2O)9-x](4-x)+ withCucurbituril; Complementarity Control through trhe Variation of x. In: Inorg. Chim. Acta, 2002, 31-38
2002O. A. Gerasko, D. G. Samsonenko, Vladimir Fedin: Supramolecular chemistry of cucurbiturils. In: Russ. Chem. Rev., 2002, 840-861
2002O. A. Gerasko, D. G. Samsonenko, A. A. Sharonova, A. V. Virovets, J. Lipkowski, Vladimir Fedin: Synthesis and crystal structure of supramolecular adduct of tetraneclear uranyl chloride aquacomplex with macrocyclic cavitand cucurbituril. In: Russ. Chem. Bull., 2002, 346-349
2002I. V. Kalinina, N. V. Pervukhina, N. V. Podberezskaya, Vladimir Fedin: Synthesis and crystal structure of the telluride cubane clusters [Zn(NH3)4]3[Mo4Te4(CN)12] and [Cd(NH3)4]3[W4Te4(CN)12]. In: Russ. J. Coord. Chem., 2002, 389-393
2001D. G. Samsonenko, A. A. Tripolskaya, M. N. Sokolov, A. V. Virovets, Vladimir Fedin: Crystal structure of supramolecular complex of Ca2+ with cucurbituril: {[Ca(H2O)3(HSO4)(CH3OH)]2(C36N24O12H36)}(HSO4)2 4H2O. In: Russ. J. Coord. Chem., 2001, 10-15
2001D. G. Samsonenko, M. N. Sokolov, A. V. Virovets, N. V. Pervukhina, Vladimir Fedin Isolation and Structural Characterization ov new In(III) Aqua Complexes: trans-[InCl2(H2=)4]+ and trans-[InCl4(H2O)2] as Supramolecular Adducts with Cucurbituril, and Related Studies. In: Eur. J. Inorg. Chem., 2001, 167-172
2001M. N. Sokolov, A. V. Virovets, D. N. Dybtsev, E. V. Chubarova, Vladimir Fedin, D. Fenske: Phosphoruous Acid and Arsenious Acid as Ligands. In: Inorg. Chem., 2001, 4816-4817
2001Vladimir Fedin, M. Sokolov, G. J. Lamprecht, R. Hernandez-Molina, Mi-Sook Seo, A. V. Virovets, W. Clegg, A. G. Sykes: Preparation, Structure and Properties of the Corner-Shared Double Cubes [Mo6HgQ8(H2O)18]8+(Q=S, Se) and Tungsten Analogues. In: Inorg. Chem., 2001, 6598-6603
2001Mi-Dook Seo, Vladimir Fedin, M. N. Sokolov, R. Hernandez-Molina, A. Sokolowski, M. R. J. Elsegood, W. Clegg, A. G. Sykes: Preparation, Structure, and Reactivity of Ge-Containing Hetrometallic Cube Derivatives of [M3E4(H2O)9]4+ (M=Mo, W; E=S, Se). In: Inorg. Chem., 2001, 6115-6122
2001Vladimir Fedin, J. Czyzniewska, R. Prins, Th. Weber: Supported molybdenumsulfur cluster compounds as precursors for HDS catalysts. In: Applied Catalysis A-General, 2001, 123-132
2001D. N. Dybtsev, O. A. Gerasko, A. V. Virovets, M. N. Sokolov, T. Weber, Vladimir Fedin: Supramolecular Adduct of the Heterometal Cubane Complex [CIPdMo3S4(H2O)6Cl3] with the Macrocyclic Cavitand Cucurbituril: Synthesis and Crystal Structure. In: Zh. Neorg. Khim., 2001, 908-914
2001D. G. Samsonenko, A. V. Virovets, A. A. Sharonova, Vladimir Fedin, D. Fenske: Synthesis and crystal structure of supramolecular adduct of the cluster complex [µo3O4(H2O)6Cl3]+ with macrocycle cavitand cucurbituril. In: Russian Chem. Bull., 2001, 475-477
2001M. N. Sokolov, D. N. Dybtsev, A. V. Virovets, W. Clegg, Vladimir Fedin: Synthesis and the crystal structure of the supramolecular complex [Cl3InW3S4(H2O)9]2+ with cucurbituril. In: Russian Chem. Bull., 2001, 1144-1147
2001Vladimir Fedin, I. V. Kalinina, A. V. Virovets, D. Fenske Synthesis, structure and properties of nionium and tantalum telluride cuboidal complexes [M4(µ4-O)(µ3-Te)4(CN)12]6- (M=Nb, Ta). In: Russian Chem. Bull, 2001, 892-896
2001Vladimir Fedin, I. V. Kalinina, A. V. Virovets, D. Fenske: Sysnthesis and structure of polymeric cyanide cluster compound [Mn(H2O)4]3[W4S4(CN)12] nH2O containing very large cavities. In: Russian Chem. Bull, 2001, 1525-1528
2000Vladimir Fedin, A. V. Virovets, I. V. Kalinina, V. N. Ikorskii, M. R. J. Elsogood, W. Clegg: A Three-Dimensional Cyano-Bridged Cluster-Metal Coordination Compound with large Cavities. In: Eur. J. Inorg. Chem., 2000, 2341-2343
2000A. V. Virovets, D. G. Samsonenko, Vladimir Fedin, W. Clegg: A new cluster complex, (NH4)6[Mo3Se4(CN)12] 6H2O, containing a tetranuclear mixed-valence molybdenum core. In: Acta Cristallographica, Section C, 2000, 272-273
2000Vladimir Fedin, A. V. Virovets, D. N. Dybtsev, O. A. Gerasko, K. Hegetschweiler, M. R. J. Elsegood, W. Clegg: A supramolecular approach to the crystallization of chalcogenido bridged cluster aqua ions: synthesis and structure of a cucurbituril adduct of the di-µ-disulfido NbIV2 aqua ion [Nb2(µ-S2)2(H2O)8]4+. In: Inorg. Chim Acta, 2000, 301-304
2000O. A. Gerasko, A. V. Virovets, D. N. Dybtsev, W. Clegg, Vladimir Fedin: Crystal structure of (H2O)4[W3S7Cl6]2(C36N24O12H36) 8H2O - a supramolecular cluster adduct with cucurbituril. In: Koord. Khim, 2000, 512-515
2000M. N. Sokolov, A. V. Virovets, D. N. Dybtsev, O. A. Gerasko, Vladimir Fedin, R. Hernandez-Molina, W. Clegg, A. G. Sykes: Metal incorporation into and dimerization of M3E4 clusters (M=Mo, W; E=S, Se) in supramolecular assemblies with cucurbiturila molecular model of intercalation. In: Angew. Chem., Int. Ed. Engl., 2000, 1659-1661
2000Vladimir Fedin, A. V. Virovets, M. N. Sokolov, D. N. Dybtsev, O. A. Gerasko, W. Clegg: Supramolecular Asembleis Based on Cucurbituril Adducts of Hydrogen-Bonded Molybdenum and Tungsten Incomplete Cuboidal Aqua Complexes. In: Inorg. Chem., 2000, 2227-2230
2000N. V. Pervukhina, N. V. Podberezskaya, I. V. Kalinina, Vladimir Fedin,: Synthesis and molecular and crystal structure of K4.5 {[Mo3(µ3-Te)(µ2-Te2)3(CN)6]l}l1,5 3H2O and Cs3{[Mo3(µ3-Te)(µ2-Te)3(CN)6]l}2H2O. In: J. Struct. Chem., 2000, 843-850
2000M.N. Sokolov, D. N. Dybtsev, A. V. Virovets, K. Hegetschweiler, Vladimir Fedin: Synthesis and the crystal structure of a supramolecular adduct of the cubane cluster [CIPdMo3 Se4(H2O)7Dl2]+ with macrocyclic cavitand cucurbituril. In: Russian Chemical Bulletin, 2000, 1906-1910
2000Vladimir Fedin, A. V. Virovets, D. G. Samsonenko, I. V. Kalinina, D. Y. Naumov: Synthesis, structure and properties of molybdenum and tungsten chalcogenide cubane complexes (NH4)6[M3Q4(CN)12] 6H2O(M=Mo, W; Q=S, Se). In: Russian Chemical Bulletin, 2000, 18-24
2000A. V. Virovets, I. V. Lakinina, Vladimir Fedin, D. Fenske: Tetragonal polymorphic modification of tetrakis (N,N-diethyldithiocarbamato-S,s')tellurium(IV). In: Acta Cryst., 2000, E589-E590
2000D. N. Dybtsev, O. A. Geralsko, A. V. Virovets, M. N. Sokolov, Vladimir Fedin Unexpected Guest-Controlled Formation of Two-Layered Structure in Supramolecular Adduct of [W3S4(H2O)9]4+ and Cucurbituril. In: Inorg. Chem. Commun., 2000, 345-349
2000T. V. Basova, B. A. Kolesov, D. G. Samsonenko, Vladimir Fedin, Vibrational spectra of chalcogenide cubane-type clusters of molybdenum and tungsten. In: Russ. J. Inorg. Chem., 2000, 1098
1999A. Müller, Vladimir Fedin, C. Kuhlmann, H. Bögge, M. Schmidtmann: A hydrogen-bonded cluster with 'onion-type' structure, ecapsulated and induced by a spherical cluster shell: [(H2O)nMoVI72MoV60(HCO2)30(H2O)72]42-. In: J. Chem. Soc., Chem. Commun., 1999, 927-928
1999A. Müller, Vladimir Fedin, C. Kuhlmann, H.-D. Fenske, G. Baum, H- Bögge, B. Hauptfleish: Adding stable functional complementary, nucleophilic and electrophilic clusters: a synthetic route to [{(SiW11O39)Mo3S4(H2O)3(µ-OH)}2]10- and [{P2W17O61)Mo3S4(H2O)3(µ-OH)}2]14- as examples. In: Chem. Commun., 1999, 1189-1190
1999K. G. Myakishev, M. N. Sokolov, Vladimir Fedin, G. S. Voronina, V. V. Volkov: On mechanochemical synthesis of cluster thiobromide complex [(C2H5)4N]2[Mo3(µ3-S)(µ2-S2)3Br6]. In: Zh. Niorg. Khim, 1999, 233-236
1999A. Müller, S. K. Das, Vladimir Fedin, E. Krickemeyer, C. Beughold, H. Bögge, M. Schmidtmann, B. Hauptfleish: Rapid and simple isolation of the crystalline molybdenum-blue compounds with discrete and linked nanosized ring-shaped anions. In: Z. Anorg. Allg. Chem., 1999, 1187-1192
1999Vladimir Fedin, D. N. Dybtsev: Synthesis and properties of selenobridged cuboidal indium and tin aqua complexes. In: Zh. Neorg. Khim., 1999, 743-746
1999Vladimir Fedin, et al.: Synthesis, Structure, and Properties of Molybdenum and Tungsten Cyano Complexes with Cuboidal M4(µ-E)4 (M=Mo, W; E=S, Se, Te) Cores. In: Inorg. Chem., 1999, 1956-1967
1998Vladimir Fedin, I. V. Kalinina, A. V. virovets, N. V. Podberezskaya, A. G. Sykes: First complex with suboidal-type M4Te4 (M=Mo, W) cluster cores: synthesis and structure of K7[Mo4Te4(CN)12] 11H2O and K6[W4Te4(CN)12] 5H2O. In: J. Chem. Soc., Chem. Commun., 1998, 237-238
1998Vladimir Fedin, M. N. Sikilov, A. V. Virovets, N. V. Podberezskaya, V. E. Fedorov: New efficient synthesis of the trinuclear cluster [W3Se4(H2O)9]4+ and X-ray structure of the first mixed-metal seleno-bridge cubane-type tungsten cluster (Me2NH2)6[(SCN)9W3Se4SnCl3]0,5H2O. In: Inorg. Chim. Acta, 1998, 292-296
1998R. Hernandez-Molina, Vladimir Fedin, M. N. Sokolov, D. M. Saysell, A. G. Sykes: Preparation and properties of group 13 (Ga, In, Tl) heterometallic single and corner-shared double cube derivatives of [µo2S4(H2O)9]4+ and related studies. In: Inorg. Chem., 1998, 4328-4334
1998R. Hernandez-Molina, D. N. Dybtsev, Vladimir Fedin, M. R. J. Elsegood, W. Clegg, A. G. Sykes: Preparation, structure, and reactivity of heterometallic Sn-containing single- and double-cube derivatives of [µo3Se4(H2O)9]4+ and [W3Se4(H2O)9]4+. In: Inorg. Chem., 1998, 2995-3001
1998M. J. Mayor-Lopez, J. Weber, K. Hegetschweiler, M. D. Meienberer, F. Joho, S. Leoni, R. Nesper, G. J. Reiss, W. Frank, Ba. A. Kolesov, Vladimir Fedin, V. E. Fedorov: Structure and reactivity of [Mo3-µ3S-(µS2)3]4+ complexes: Quantrum chemical calculations; X-ray structural characterization, and Raman spectroscopic measurements. In: Inor. Chem., 1998, 2633-2644
1998Vladimir Fedin, I. f. Kalinina, A. V. virovets, N. V. Podberezskaya, I. S. Neretin, Y. L. Slovokhotov: Synthesis and structure of a tetranuclear niobium cuzboidal cluster with a central µ4-O ligand. In: J. Chem. Soc., Chem. Commun., 1998, 2579-2580
1998Vladimir Fedin, A. V. Viroverts, A. G. Sykes: Synthesis of the first sulfidobridged octahedral rhenium (III) aqua ion [Re6S8(H2O)6]2+. In: Inorg. Chim. Acta, 1998, 228-230