Prof. Dr. Marcos de Oliveira Junior

Profile

Academic positionLecturer, Assistant Professor, Researcher
Research fieldsExperimental Condensed Matter Physics,Spectroscopy
KeywordsStructural characterization, mesoporous materials, NMR, EPR, DNP

Current contact address

CountryBrazil
CitySao Carlos
InstitutionUniversidade de Sao Paulo (USP)
InstituteInstituto de Fisica de Sao Carlos

Host during sponsorship

Prof. Dr. Gerd BuntkowskyInstitut für Physikalische Chemie, Technische Universität Darmstadt, Darmstadt
Prof. Dr. Andréa Simone Stucchi de CamargoAbteilung V: Werkstofftechnik, Bundesanstalt für Materialforschung und -prüfung (BAM), Berlin
Prof. Dr. Gerd BuntkowskyEduard Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Darmstadt
Start of initial sponsorship01/03/2018

Programme(s)

2017CAPES-Humboldt Research Fellowship Programme for Postdocs

Publications (partial selection)

2025{Olivetti Estevam da Silva}, Leandro and Silva, Lais Dantas and Zanotto, Edgar Dutra and {de Oliveira Junior}, Marcos and Manzani, Danilo: {Alkaline Earth Metal Fluorides (MgF 2 CaF 2 SrF 2 BaF 2 ) and Nb 2 O 5 Effect on the Structural and Optical Properties of New Fluorophosphoniobate Glasses}. In: ACS Omega, 2025,
2025da Silva, Leandro Olivetti Estevam and Rivera, V.A.G. and Falci, Rodrigo and Messaddeq, Youn{\`{e}}s and de {Oliveira Junior}, Marcos and Manzani, Danilo: {Fluorine alkaline earth (MgF2, CaF2, SrF2, BaF2) influence on thermal, structural, and luminescent properties of Eu3+-doped niobium phospho-fluoride glass}. In: Materials Research Bulletin, 185, 2025, 113291
2025Lozano, G. and dos Santos, J.F.M. and Mer{\'{i}}zio, L.G. and de Oliveira, M. and Messaddeq, Y and Marega, E. and Rivera, V.A.G.: {Improving laser performance at 1081 nm in Yb3+-doped tellurite glasses with low threshold}. In: Materials Research Bulletin, 189, 2025, 113458
2025Tayama, Gabriel Toshiaki and Costa, Beatriz Helena and Caixeta, F{\'{a}}bio Jos{\'{e}} and {Murback Filho}, Renato Pereira and {de Oliveira Junior}, Marcos and {Elias e Silva}, Lucas Toth and Messaddeq, Younes and Santagneli, Silvia Helena: {Luminescent Eu3+ doped silicate-aluminum-borate hybrid materials obtained by photopolymerization of sol-gel resins}. In: Journal of Sol-Gel Science and Technology, 2025,
2025Wissel, Till and R{\"{o}}sler, Lorenz and Brodrecht, Martin and H{\"{o}}fler, Mark V. and Herr, Kevin and de Oliveira, Marcos and Klimavicius, Vytautas and Ebert, Martin and Breitzke, Hergen and Hoffmann, Markus and Buntkowsky, Gerd and Gutmann, Torsten: {Novel Heterogeneous Pd Catalysts for Cross‐Coupling Reactions in Biocompatible Media: Structural Insights from Solid‐State NMR Techniques}. In: ChemCatChem, 17, 2025, e202401511
2025Bradtm{\"{u}}ller, Henrik and {Gir{\'{o}}n Lange}, Esther and Zeidler, Anita and de Oliveira,, Marcos and Pena, Rafaella Bartz and Eckert, Hellmut and Mohammadi, Hesameddin and Cuello, Gabriel J and Salmon, Philip S: {Structure of alkali magnesium, zinc, and calcium metasilicate glasses}. In: The Journal of Chemical Physics, 163, 2025, 204502
2024Herr, Kevin and H{\"{o}}fler, Mark V. and Heise, Henrike and Aussenac, Fabien and Kornemann, Felix and Rosenberger, David and Brodrecht, Martin and de Oliveira, Marcos and Buntkowsky, Gerd and Gutmann, Torsten: {Biradicals based on PROXYL containing building blocks for efficient dynamic nuclear polarization in biotolerant media}. In: Journal of Magnetic Resonance Open, 20, 2024, 100152
2024{Gabriel de Assis}, Renan and {de Oliveira Junior}, Marcos and Escote, M{\'{a}}rcia Tsuyama and Pinheiro, Carlos Bas{\'{i}}lio and Acu{\~{n}}a, Jos{\'{e}} Javier S{\'{a}}ez and Ferreira, Fabio Furlan and {Sucupira Pedroza}, Luana and Brochsztain, Sergio and de Queiroz, Thiago Branquinho: {Preparation and Characterization of a Disilylated Naphthalenediimide Molecular Crystal: Perspectives for Organosilica Mesoporous Materials}. In: ACS Applied Engineering Materials, 2, 2024, 1976--1986
2023Capelo, Renato Grigolon and {Santos Baltieri}, Ricardo and de Oliveira, Marcos and Manzani, Danilo: {Exploring the Influence of ZnF 2 on Zinc-Tellurite Glass: Unveiling Changes in OH Content, Structure, and Optical Properties}. In: ACS Omega, 8, 2023, 35266--35274
2023Lodi, Thiago A. and Galleani, Gustavo and {de Oliveira, Jr.}, Marcos and Santagneli, Silvia H. and Eckert, Hellmut and de Camargo, Andrea S.S. and Junior, Marcos de Oliveira and Santagneli, Silvia H. and Eckert, Hellmut and de Camargo, Andrea S.S.: {Preparation, characterization, and structural studies of new sodium gallium tungstate phosphate glasses}. In: Journal of Non-Crystalline Solids, 603, 2023, 122100
2023{Garc{\'{i}}a Flores}, Ali F. and Munevar, Julian and {de Oliveira Junior}, Marcos and Rettori, Carlos and Urbano, Ricardo R. and de Queiroz, Thiago B.: {Relaxation Processes in Rare-Earth-Doped $\alpha$-NaYF 4 Nanoparticles by Nuclear Magnetic Resonance Spectroscopy}. In: The Journal of Physical Chemistry C, 127, 2023, 18420--18430
2023Siqueira, Guilherme O and de Lima, Geraldo M. and Ara{\'{u}}jo, Francielle C and de Andrade, Fabr{\'{i}}cio V. and Moraes, Tiago B and de Oliveira, Marcos and {de Oliveira, Marcos}, Jr.: {Solid state NMR characterization of NaNbO3 and LiNbO3 nanoparticles obtained by microwave-assisted combustion}. In: Journal of Magnetic Resonance Open, 14-15, 2023, 100088
2023{Candian Firmino Marcos}, Francielle and {Fonseca Costa}, Maria Jose and {L. Catuzo}, Gabriel and {Angeli de Moraes}, Daniel and {de Oliveira Junior}, Marcos and Mastelaro, Valmor Roberto and {Mansur Assaf}, Jos{\'{e}} and Giudici, Reinaldo and {Morreira Assaf}, Elisabete: {Supported Cu catalysts on UiO-66 toward enhanced methanol selectivity by CO2 hydrogenation: Effect of Cu loading}. In: Journal of Catalysis, 427, 2023, 115104
2023Melo, G.H.A. and Dantas, N.F. and Muniz, F.R. and Manzani, D. and {de Oliveira Jr.}, M. and Pedrochi, F. and Steimacher, A.: {The effect of ZnO on the structural and radiation shielding properties in borophosphate glasses}. In: Journal of Non-Crystalline Solids, 618, 2023, 122528
2023Tayama, Gabriel Toshiaki and Santagneli, Silvia Helena and {de Oliveira Junior}, Marcos and Messaddeq, Younes: {Understanding the Microstructure Connectivity in Photopolymerizable Aluminum-Phosphate-Silicate Sol–Gel Hybrid Materials for Additive Manufacturing}. In: The Journal of Physical Chemistry C, 127, 2023, 2416--2429
2022de Oliveira, Marcos and Damasceno, Hugo and Salmon, Philip S. and Eckert, Hellmut: {Analysis and information content of quadrupolar NMR in glasses: 25Mg NMR in vitreous MgSiO3 and CaMgSi2O6}. In: Journal of Magnetic Resonance Open, 12-13, 2022, 100067
2022Klabunde, Sina and Doerenkamp, Carsten and de Oliveira, Marcos and Zeng, Zhaoyang and Eckert, Hellmut: {Inorganic-organic hybrid materials based on the intercalation of radical cations: 2-(4- N -methylpyridinium)-4,4,5,5-tetramethyl-4,5-dihydro-1 H -imidazol-1-oxyl-3- N -oxide in fluoromica clay}. In: Zeitschrift f{\"{u}}r Physikalische Chemie, 236, 2022, 961--978
2022Vilela, Raquel R. C. and Zanoni, Kassio P. S. and {de Oliveira, Jr.}, Marcos and de Vicente, F{\'{a}}bio S. and de Camargo, Andrea S. S.: {Structural and photophysical characterization of highly luminescent organosilicate xerogel doped with Ir(III) complex}. In: Journal of Sol-Gel Science and Technology, 102, 2022, 236--248
2022Mohammadi, Hesameddin and {Mendes Da Silva}, Rita and Zeidler, Anita and Gammond, Lawrence V. D. and Gehlhaar, Florian and de Oliveira, Marcos and Damasceno, Hugo and Eckert, Hellmut and Youngman, Randall E. and Aitken, Bruce G. and Fischer, Henry E. and Kohlmann, Holger and Cormier, Laurent and Benmore, Chris J. and Salmon, Philip S.: {Structure of diopside, enstatite, and magnesium aluminosilicate glasses: A joint approach using neutron and x-ray diffraction and solid-state NMR}. In: The Journal of Chemical Physics, 157, 2022, 214503
2022Serra, Ayla Roberta Borges and Casagrande, Thiago Rui and de Lima, Juliana Fonseca and de Oliveira, Marcelo Firmino and J{\'{u}}nior, Severino Alves and {de Oliveira Junior}, Marcos and Serra, Osvaldo Antonio: {Synthesis and Structural Characterization of an Amorphous and Photoluminescent Mixed Eu/Zr Coordination Compound, a Potential Marker for Gunshot Residues}. In: Sci, 4, 2022, 43
2021Morguetto, Gabriel Felipe and {de Oliveira, Jr.}, Marcos and Schneider, Jos{\'{e}} Fabi{\'{a}}n and Eckert, Hellmut: {Mixed Cs–Li–Sr Metaphosphate Glasses}. In: The Journal of Physical Chemistry C, 125, 2021, 4764--4776
2021{de Oliveira, Jr.}, Marcos and Galleani, Gustavo and Jos{\'{e}}, Claudio and Eckert, Hellmut: {Modern magnetic resonance approaches for characterizing rare-earth containing glasses and glass ceramics}. In: Journal of Non-Crystalline Solids, 552, 2021, 120438
2021Monteiro, Andreia S and {de Oliveira, Jr.}, Marcos and Santagneli, Silvia and Carcel, Carole and Gutmann, Torsten and Buntkowsky, Gerd and Man, Michel Wong Chi and Barud, Hernane S and Ribeiro, Sidney J L: {Modification of Bacterial Cellulose Membrane with 1,4-Bis(triethoxysilyl)benzene: A Thorough Physical–Chemical Characterization Study}. In: The Journal of Physical Chemistry C, 125, 2021, 4498--4508
2021de Oliveira, Marcos and Herr, Kevin and Brodrecht, Martin and Haro-Mares, Nadia Berenice and Wissel, Till and Klimavicius, Vytautas and Breitzke, Hergen and Gutmann, Torsten and Buntkowsky, Gerd: {Solvent-free dynamic nuclear polarization enhancements in organically modified mesoporous silica}. In: Physical Chemistry Chemical Physics, 23, 2021, 12559--12568
2020Gr{\"{a}}tz, Sven and {de Olivera Junior}, Marcos and Gutmann, Torsten and Borchardt, Lars: {A comprehensive approach for the characterization of porous polymers using 13 C and 15 N dynamic nuclear polarization NMR spectroscopy}. In: Physical Chemistry Chemical Physics, 22, 2020, 23307--23314
2020Santos, F P S and {de Oliveira, Jr.}, Marcos and Dousti, M Reza and Vermelho, M V D: {Effect of silver and antimony on optical properties of tungsten-phosphate glasses}. In: Journal of Luminescence, 223, 2020, 117191
2020Gala{\c{c}}o, Ayla Roberta Borges da Silva and {Tavares Jesus}, Larissa and Freire, Ricardo Oliveira and {de Oliveira Junior}, Marcos and Serra, Osvaldo Antonio: {Experimental and theoretical studies of Glyphosate detection in water by an europium luminescent complex and effective adsorption by HKUST-1 and IRMOF-3.}. In: Journal of Agricultural and Food Chemistry, 68, 2020, 9664--9672
2020Franco, Douglas F. and Fernandes, Roger Gomes and Santagneli, Silvia Helena and {De Oliveira}, Marcos and Eckert, Hellmut and Nalin, Marcelo: {Structural Study of the Germanium-Aluminum-Borate Glasses by Solid State NMR and Raman Spectroscopies}. In: Journal of Physical Chemistry C, 124, 2020, 24460--24469
2019Benndorf, Christopher and de Oliveira, Marcos and Doerenkamp, Carsten and Haarmann, Frank and Fickenscher, Thomas and K{\"{o}}sters, Jutta and Eckert, Hellmut and P{\"{o}}ttgen, Rainer: {11 B and 89 Y solid state MAS NMR spectroscopic investigations of the layered borides YTB 4 (T = Mo, W, Re)}. In: Dalton Transactions, 48, 2019, 1118--1128
2019Brodrecht, Martin and Herr, Kevin and Bothe, Sarah and de Oliveira, Marcos and Gutmann, Torsten and Buntkowsky, Gerd: {Efficient Building Blocks for Solid‐Phase Peptide Synthesis of Spin Labeled Peptides for Electron Paramagnetic Resonance and Dynamic Nuclear Polarization Applications}. In: ChemPhysChem, 20, 2019, cphc.201900211
2019{Munhoz F. V. L.}, Joao and Santagneli, Silvia Helena and {de Oliveira, Jr.}, Marcos and Rodrigues, Ana Candida Martins and Eckert, Hellmut and Nalin, Marcelo: {Glasses in the NaPO3-WO3-NaF ternary system: preparation, physical properties and structural studies}. In: Journal of Non-Crystalline Solids, 505, 2019, 379--389
2019Nguyen, Khoa D. and Kutzscher, Christel and Ehrling, Sebastian and Senkovska, Irena and Bon, Volodymyr and {de Oliveira, Jr.}, Marcos and Gutmann, Torsten and Buntkowsky, Gerd and Kaskel, Stefan: {Insights into the role of zirconium in proline functionalized metal-organic frameworks attaining high enantio- and diastereoselectivity}. In: Journal of Catalysis, 377, 2019, 41--50
2019Benndorf, Christopher and {de Oliveira, Jr.}, Marcos and Bradtm{\"{u}}ller, Henrik and Stegemann, Frank and P{\"{o}}ttgen, Rainer and Eckert, Hellmut: {Rare-earth solid-state NMR spectroscopy of intermetallic compounds: The case of the 175Lu isotope}. In: Solid State Nuclear Magnetic Resonance, 101, 2019, 63--67
2019{de Oliveira, Jr.}, Marcos and Seeburg, Dominik and Wei{\ss}, Jana and Wohlrab, Sebastian and Buntkowsky, Gerd and Bentrup, Ursula and Gutmann, Torsten: {Structural characterization of vanadium environments in MCM-41 molecular sieve catalysts by solid state 51V NMR}. In: Catalysis Science & Technology, 9, 2019, 6180--6190
2018{de Oliveira, Jr.}, Marcos and Amjad, Raja Junaid Mohammad and de Camargo, Andrea Simone Stucchi and Eckert, Hellmut: {Network Former Mixing Effects in Heavy Metal Oxide Glasses: Structural Characterization of Lead Zinc Phosphotellurite Glasses Using NMR and EPR Spectroscopies}. In: The Journal of Physical Chemistry C, 122, 2018, 23698−23711
2018de Oliveira, Marcos and Oliveira, Janete Schultz and Kundu, Swarup and Machado, Norma Maria Pereira and Rodrigues, Ana Candida M. and Eckert, Hellmut: {Network former mixing effects in ion-conducting lithium borotellurite glasses: Structure/property correlations in the system (Li2O) [2(TeO2) (B2O3)1−]1−}. In: Journal of Non-Crystalline Solids, 482, 2018, 14--22
2018{de Oliveira, Jr.}, Marcos and Aitken, Bruce and Eckert, Hellmut: {Structure of P2O5 –SiO2 Pure Network Former Glasses Studied by Solid State NMR Spectroscopy}. In: The Journal of Physical Chemistry C, 122, 2018, 19807--19815
2017Dierkes, Tobias and Seidel, Stefan and Benndorf, Christopher and Heletta, Lukas and {de Oliveira, Jr.}, Marcos and Holtkamp, Michael and Karst, Uwe and Block, Theresa and J{\"{u}}stel, Thomas and Eckert, Hellmut and P{\"{o}}ttgen, Rainer: {Mixed europium valence in Eu0.937Ba8[BN2]6– Structure and spectroscopic behavior}. In: Solid State Sciences, 70, 2017, 86--92
2017Schmitt, Martin K. and Janka, Oliver and P{\"{o}}ttgen, Rainer and Benndorf, Christopher and {de Oliveira, Jr.}, Marcos and Eckert, Hellmut and Pielnhofer, Florian and Tragl, Amadeus-Samuel and Weihrich, Richard and Joachim, Bastian and Johrendt, Dirk and Huppertz, Hubert: {Mo2B4O9 -Connecting Borate and Metal-Cluster Chemistry}. In: Angewandte Chemie International Edition, 56, 2017, 6449--6453
2017Galleani, Gustavo and Santagneli, Silvia Helena and Messaddeq, Younes and {de Oliveira, Jr.}, Marcos and Eckert, Hellmut and Ren, J. and Zhang, L. and Eckert, H. and Gan, Z. and Hoatson, G.: {Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties}. In: Physical Chemistry Chemical Physics, 19, 2017, 21612--21624
2017Eusterwiemann, Steffen and Doerenkamp, Carsten and Dresselhaus, Thomas and Janka, Oliver and {de Oliveira Jr.}, M. and Daniliuc, C. G. and Eckert, Helmut and Neugebauer, Johannes and P{\"{o}}ttgen, R. and Studer, Armido: {Strong intermolecular antiferromagnetic verdazyl–verdazyl coupling in the solid state}. In: Physical Chemistry Chemical Physics, 19, 2017, 15681--15685
2017Zhang, Ruili and {de Oliveira, Jr.}, Marcos and Wang, Zaiyang and Fernandes, Roger Gomes and de Camargo, Andrea Simone Stucchi and Ren, Jinjun and Zhang, Long and Eckert, Hellmut: {Structural Studies of Fluoroborate Laser Glasses by Solid State NMR and EPR Spectroscopies}. In: The Journal of Physical Chemistry C, 121, 2017, 741--752
2017{de Oliveira, Jr.}, Marcos and Gon{\c{c}}alves, T{\'{a}}ssia S. and Ferrari, Cynthia and Magon, Claudio Jos{\'{e}} and Pizani, Paulo S. and de Camargo, Andrea S. S. and Eckert, Hellmut: {Structure–Property Relations in Fluorophosphate Glasses: An Integrated Spectroscopic Strategy}. In: The Journal of Physical Chemistry C, 121, 2017, 2968--2986
2016{de Oliveira, Jr.}, Marcos and Knitsch, Robert and Sajid, Muhammad and Stute, Annika and Elmer, Lisa-Maria and Kehr, Gerald and Erker, Gerhard and Magon, Claudio J and Jeschke, Gunnar and Eckert, Hellmut: {Aminoxyl Radicals of B/P Frustrated Lewis Pairs: Refinement of the Spin-Hamiltonian Parameters by Field- and Temperature-Dependent Pulsed EPR Spectroscopy.}. In: PloS one, 11, 2016, e0157944
2016de Vries, Wilke and Doerenkamp, Carsten and Zeng, Zhaoyang and {de Oliveira, Jr.}, Marcos and Niehaus, Oliver and P{\"{o}}ttgen, Rainer and Studer, Armido and Eckert, Hellmut: {Synthesis and characterization of amorphous mesoporous silica using TEMPO-functionalized amphiphilic templates}. In: Journal of Solid State Chemistry, 237, 2016, 93--98
2015{de Oliveira, Jr.}, Marcos and Uesbeck, Tobias and {S. Gon{\c{c}}alves}, T{\'{a}}ssia and Magon, Jos{\'{e}} Cl{\'{a}}udio and {S. Pizani}, Paulo and de Camargo, Andrea S.S. and Eckert, Hellmut: {Network Structure and Rare-Earth Ion Local Environments in Fluoride Phosphate Photonic Glasses Studied by Solid-State NMR and Electron Paramagnetic Resonance Spectroscopies}. In: The Journal of Physical Chemistry C, 119, 2015, 24574--24587
2015Ferreira-Neto, Elias P. and Ullah, Sajjad and de Carvalho, Flavio L.S. and de Souza, Adriano L. and {de Oliveira, Jr.}, Marcos and Schneider, Jos{\'{e}} F. and Mascarenhas, Yvonne P. and Jorge, Alberto M. and Rodrigues-Filho, Ubirajara P.: {Preparation, characterization and photochromic behavior of phosphotungstic acid-ormosil nanocomposites}. In: Materials Chemistry and Physics, 153, 2015, 410--421
2015{de Oliveira, Jr.}, Marcos and Wiegand, Thomas and Elmer, Lisa-maria and Sajid, Muhammad and Kehr, Gerald and Erker, Gerhard and Magon, Claudio Jos{\'{e}} and Eckert, Hellmut: {Solid-state EPR strategies for the structural characterization of paramagnetic NO adducts of frustrated Lewis pairs (FLPs)}. In: Journal of Chemical Physics, 142, 2015, 124201
2015Gon{\c{c}}alves, T{\'{a}}ssia S. and {Moreira Silva}, Raphaell J. and {de Oliveira, Jr.}, Marcos and Ferrari, Cynthia R. and Poirier, G{\"{a}}el Y. and Eckert, Hellmut and de Camargo, Andrea S.S.: {Structure-property relations in new fluorophosphate glasses singly- and co-doped with Er3+ and Yb3+}. In: Materials Chemistry and Physics, 157, 2015, 45--55
2014de Oliveira, Marcos and Rodrigues-Filho, Ubirajara Pereira and Schneider, J: {Thermal Transformations and Proton Species in 12-Phosphotungstic Acid Hexahydrate Studied by 1 H and 31 P Solid-State Nuclear Magnetic Resonance}. In: The Journal of Physical Chemistry C, 118, 2014, 11573--11583
2011{de Oliveira, Jr.}, Marcos and {De Souza}, a. Lopes and Schneider, J. and Rodrigues-Filho, U. Pereira: {Local Structure and Photochromic Response in Ormosils Containing Dodecatungstophosphoric Acid}. In: Chemistry of Materials, 23, 2011, 953--963