Dr. Kushal Sengupta

Profil

Derzeitige StellungProfessor W-1 und Äquivalente
FachgebietAnorganische Molekülchemie,Elektrochemie
Keywordselectrocatalysis, Nitrogenase, reaction mechanism, intermediates, bioelectrochemistry
Auszeichnungen

2020: AvH fellowship

Aktuelle Kontaktadresse

LandDeutschland
OrtMülheim an der Ruhr
Universität/InstitutionMax-Planck-Institut für Chemische Energiekonversion
Institut/AbteilungAbteilung Anorganische Spektroskopie
Websitehttps://www.cec.mpg.de/en/research/inorganic-spectroscopy/dr-kushal-sengupta

Gastgeber*innen während der Förderung

Prof. Dr. Serena DeBeerAbteilung Anorganische Spektroskopie, Max-Planck-Institut für Chemische Energiekonversion, Mülheim an der Ruhr
Beginn der ersten Förderung01.04.2021

Programm(e)

2020Humboldt-Forschungsstipendien-Programm für Postdocs

Publikationen (Auswahl)

2025Kushal Sengupta, Justin P Joyce, Laure Decamps, Liqun Kang, Ragnar Bjornsson, Olaf Rüdiger, Serena DeBeer: Investigating the Molybdenum Nitrogenase Mechanistic Cycle Using Spectroelectrochemistry. In: Journal of the American Chemical Society, 147, 2025, 2099-2114
2024Udit Kumar Chakraborty, Youngchan Park, Kushal Sengupta, Won Jung, Chandra P Joshi, Danielle H Francis, Peng Chen: A ‘through-DNA’mechanism for co-regulation of metal uptake and efflux. In: Nature Communications, 15, 2024, 1-11
2024Isis M Wahl, Kushal Sengupta, Maurice van Gastel, Laure Decamps, Serena DeBeer: Understanding the P‐cluster of Vanadium Nitrogenase: an EPR and XAS study of the holo vs. apo forms of the enzyme. In: ChemBioChem, 2024, e202400833
2022Mittra, Kaustuv and Samanta, Subhra and Singha, Asmita and Sengupta, Kushal and Chatterjee, Sudipta: Oxygen reduction reaction by metalloporphyrins. Elsevier, 2022
2022Ahmed, Md Estak and Chattopadhyay, Samir and Chatterjee, Sudipta and Sengupta, Kushal: Oxygen reduction reaction in enzymatic biofuel cells. Elsevier, 2022
2020Jung, Won and Sengupta, Kushal and Wendel, Brian M and Helmann, John D and Chen, Peng: Biphasic unbinding of a metalloregulator from DNA for transcription (de) repression in Live Bacteria. In: Nucleic Acids Research, 48, 2020, 2199--2208
2020Chatterjee, Sudipta and Sengupta, Kushal: Carbon-based electrodes for direct methanol fuel cells. Elsevier, 2020
2020Fu, Bing and Sengupta, Kushal and Genova, Lauren A and Santiago, Ace George and Jung, Won and Krzemi{\'n}ski, {\L}ukasz and Chakraborty, Udit Kumar and Zhang, Wenyao and Chen, Peng: Metal-induced sensor mobilization turns on affinity to activate regulator for metal detoxification in live bacteria. In: Proceedings of the National Academy of Sciences, 117, 2020, 13248--13255
2018Sarkar, Ankita and Sengupta, Kushal and Chatterjee, Sudipta and Seal, Manas and Faller, Peter and Dey, Somdatta Ghosh and Dey, Abhishek: Metal Binding to A$\beta$ Peptides Inhibits Interaction with Cytochrome c: Insights from Abiological Constructs. In: ACS Omega, 3, 2018, 13994--14003
2017Chatterjee, Sudipta and Sengupta, Kushal and Mondal, Biswajit and Dey, Subal and Dey, Abhishek: Factors Determining the Rate and Selectivity of 4e--/4H+ Electrocatalytic Reduction of Dioxygen by Iron Porphyrin Complexes. In: Accounts of chemical research, 50, 2017, 1744--1753
2016Chatterjee, Sudipta and Sengupta, Kushal and Bandyopadhyay, Sabyasachi and Dey, Abhishek: Ammonium tetrathiomolybdate as a novel electrode material for convenient tuning of the kinetics of electrochemical O 2 reduction by using iron--porphyrin catalysts. In: Journal of Materials Chemistry A, 4, 2016, 6819--6823
2016Mukherjee, Sohini and Sengupta, Kushal and Bandyopadhyay, Sabyasachi and Dey, Abhishek: Bio-inspired Electrodes. world scientific, 2016
2016Sengupta, Kushal and Chatterjee, Sudipta and Dey, Abhishek: Catalytic H2O2 Disproportionation and Electrocatalytic O2 Reduction by a Functional Mimic of Heme Catalase: Direct Observation of Compound 0 and Compound I in Situ. In: ACS Catalysis, 6, 2016, 1382--1388
2016Sengupta, Kushal and Chatterjee, Sudipta and Dey, Abhishek: In Situ Mechanistic Investigation of O2 Reduction by Iron Porphyrin Electrocatalysts Using Surface-Enhanced Resonance Raman Spectroscopy Coupled to Rotating Disk Electrode (SERRS-RDE) Setup. In: ACS Catalysis, 6, 2016, 6838--6852
2016Mittra, Kaustuv and Sengupta, Kushal and Singha, Asmita and Bandyopadhyay, Sabyasachi and Chatterjee, Sudipta and Rana, Atanu and Samanta, Subhra and Dey, Abhishek: Second sphere control of spin state: Differential tuning of axial ligand bonds in ferric porphyrin complexes by hydrogen bonding. In: Journal of inorganic biochemistry, 155, 2016, 82--91
2015Chatterjee, Sudipta and Sengupta, Kushal and Samanta, Subhra and Das, Pradip Kumar and Dey, Abhishek: Concerted Proton--Electron Transfer in Electrocatalytic O2 Reduction by Iron Porphyrin Complexes: Axial Ligands Tuning H/D Isotope Effect. In: Inorganic chemistry, 54, 2015, 2383--2392
2015Chatterjee, Sudipta and Sengupta, Kushal and Hematian, Shabnam and Karlin, Kenneth D and Dey, Abhishek: Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a “Bridging Peroxo” Intermediate Involved in Facile 4e--/4H+ O2-Reduction. In: Journal of the American Chemical Society, 137, 2015, 12897--12905
2014Bandyopadhyay, Sabyasachi and Rana, Atanu and Mittra, Kaustuv and Samanta, Subhra and Sengupta, Kushal and Dey, Abhishek: Effect of Axial Ligand, Spin State, and Hydrogen Bonding on the Inner-Sphere Reorganization Energies of Functional Models of Cytochrome P450. In: Inorganic chemistry, 53, 2014, 10150--10158
2014Sengupta, Kushal and Chatterjee, Sudipta and Mukherjee, Soumya and Dey, Somdatta Ghosh and Dey, Abhishek: Heme bound amylin self-assembled monolayers on an Au electrode: an efficient bio-electrode for O 2 reduction to H 2 O. In: Chemical Communications, 50, 2014, 3806--3809
2014Sengupta, Kushal and Chatterjee, Sudipta and Pramanik, Debajyoti and Dey, Somdatta Ghosh and Dey, Abhishek: Self-assembly of stable oligomeric and fibrillar aggregates of A$\beta$ peptides relevant to Alzheimer's disease: morphology dependent Cu/heme toxicity and inhibition of PROS generation. In: Dalton Transactions, 43, 2014, 13377--13383
2014Santra, Ramesh Chandra and Sengupta, Kushal and Dey, Rajdip and Shireen, Tahsina and Das, Piyal and Guin, Partha Sarathi and Mukhopadhyay, Kasturi and Das, Saurabh: X-ray crystal structure of a Cu (II) complex with the antiparasitic drug tinidazole, interaction with calf thymus DNA and evidence for antibacterial activity. In: Journal of Coordination Chemistry, 67, 2014, 265--285
2013Chatterjee, Sudipta and Sengupta, Kushal and Dey, Subal and Dey, Abhishek: Ammonium Tetrathiomolybdate: A Versatile Catalyst for Hydrogen Evolution Reaction from Water under Ambient and Hostile Conditions. In: Inorganic chemistry, 52, 2013, 14168--14177
2013Mondal, Biswajit and Sengupta, Kushal and Rana, Atanu and Mahammed, Atif and Botoshansky, Mark and Dey, Somdatta Ghosh and Gross, Zeev and Dey, Abhishek: Cobalt Corrole Catalyst for Efficient Hydrogen Evolution Reaction from H2O under Ambient Conditions: Reactivity, Spectroscopy, and Density Functional Theory Calculations. In: Inorganic chemistry, 52, 2013, 3381--3387
2013Sengupta, Kushal and Chatterjee, Sudipta and Samanta, Subhra and Dey, Abhishek: Direct observation of intermediates formed during steady-state electrocatalytic O2 reduction by iron porphyrins. In: Proceedings of the National Academy of Sciences, 110, 2013, 8431--8436
2013Chatterjee, Sudipta and Sengupta, Kushal and Samanta, Subhra and Das, Pradip Kumar and Dey, Abhishek: Electrocatalytic O2 Reduction Reaction by Synthetic Analogues of Cytochrome P450 and Myoglobin: In-Situ Resonance Raman and Dynamic Electrochemistry Investigations. In: Inorganic chemistry, 52, 2013, 9897--9907
2013Samanta, Subhra and Das, Pradip Kumar and Chatterjee, Sudipta and Sengupta, Kushal and Mondal, Biswajit and Dey, Abhishek: O2 Reduction Reaction by Biologically Relevant Anionic Ligand Bound Iron Porphyrin Complexes. In: Inorganic chemistry, 52, 2013, 12963--12971
2013Chatterjee, Sudipta and Sengupta, Kushal and Bhattacharyya, Sohini and Nandi, Amrit and Samanta, Subhra and Mittra, Kaustuv and Dey, Abhishek: Photophysical and ligand binding studies of metalloporphyrins bearing hydrophilic distal superstructure. In: Journal of Porphyrins and Phthalocyanines, 17, 2013, 210--219
2013Sengupta, Kushal and Chatterjee, Sudipta and Samanta, Subhra and Bandyopadhyay, Sabyasachi and Dey, Abhishek: Resonance Raman and electrocatalytic behavior of thiolate and imidazole bound iron porphyrin complexes on self assembled monolayers: Functional modeling of cytochrome P450. In: Inorganic chemistry, 52, 2013, 2000--2014
2013Samanta, Subhra and Mittra, Kaustuv and Sengupta, Kushal and Chatterjee, Sudipta and Dey, Abhishek: Second Sphere Control of Redox Catalysis: Selective Reduction of O2 to O2--or H2O by an Iron Porphyrin Catalyst. In: Inorganic chemistry, 52, 2013, 1443--1453
2012Mittra, Kaustuv and Chatterjee, Sudipta and Samanta, Subhra and Sengupta, Kushal and Bhattacharjee, Hridaynath and Dey, Abhishek: A hydrogen bond scaffold supported synthetic heme Fe III--O 2- adduct. In: Chemical Communications, 48, 2012, 10535--10537
2012Samanta, Subhra and Sengupta, Kushal and Mittra, Kaustuv and Bandyopadhyay, Sabyasachi and Dey, Abhishek: Selective four electron reduction of O 2 by an iron porphyrin electrocatalyst under fast and slow electron fluxes. In: Chemical Communications, 48, 2012, 7631--7633
2012Pramanik, Debajyoti and Sengupta, Kushal and Mukherjee, Soumya and Dey, Somdatta Ghosh and Dey, Abhishek: Self-assembled monolayers of A$\beta$ peptides on Au electrodes: an artificial platform for probing the reactivity of redox active metals and cofactors relevant to Alzheimer’s disease. In: Journal of the American Chemical Society, 134, 2012, 12180--12189
2012Mukherjee, Sohini and Sengupta, Kushal and Das, Mahua Rani and Jana, Siddhartha S and Dey, Abhishek: Site-specific covalent attachment of heme proteins on self-assembled monolayers. In: JBIC Journal of Biological Inorganic Chemistry, 17, 2012, 1009--1023